This paper is published in Volume-2, Issue-6, 2016
Area
Chemistry
Author
Rafia Ahmad, U. N.Tripath
Org/Univ
M. L. K. P. G College, Balrampur, India
Keywords
1-10-phenanthroline ; 2,2 -bipyridyll.
Citations
IEEE
Rafia Ahmad, U. N.Tripath. Synthesis and Characterization of O-Alkyl ,O-Aryl and O-Cycloalkyl Trithiophosphato Derivatives of Lanthanum (III) Chloride and their Adduct with Nitrogen Donar Bases, International Journal of Advance Research, Ideas and Innovations in Technology, www.IJARIIT.com.
APA
Rafia Ahmad, U. N.Tripath (2016). Synthesis and Characterization of O-Alkyl ,O-Aryl and O-Cycloalkyl Trithiophosphato Derivatives of Lanthanum (III) Chloride and their Adduct with Nitrogen Donar Bases. International Journal of Advance Research, Ideas and Innovations in Technology, 2(6) www.IJARIIT.com.
MLA
Rafia Ahmad, U. N.Tripath. "Synthesis and Characterization of O-Alkyl ,O-Aryl and O-Cycloalkyl Trithiophosphato Derivatives of Lanthanum (III) Chloride and their Adduct with Nitrogen Donar Bases." International Journal of Advance Research, Ideas and Innovations in Technology 2.6 (2016). www.IJARIIT.com.
Rafia Ahmad, U. N.Tripath. Synthesis and Characterization of O-Alkyl ,O-Aryl and O-Cycloalkyl Trithiophosphato Derivatives of Lanthanum (III) Chloride and their Adduct with Nitrogen Donar Bases, International Journal of Advance Research, Ideas and Innovations in Technology, www.IJARIIT.com.
APA
Rafia Ahmad, U. N.Tripath (2016). Synthesis and Characterization of O-Alkyl ,O-Aryl and O-Cycloalkyl Trithiophosphato Derivatives of Lanthanum (III) Chloride and their Adduct with Nitrogen Donar Bases. International Journal of Advance Research, Ideas and Innovations in Technology, 2(6) www.IJARIIT.com.
MLA
Rafia Ahmad, U. N.Tripath. "Synthesis and Characterization of O-Alkyl ,O-Aryl and O-Cycloalkyl Trithiophosphato Derivatives of Lanthanum (III) Chloride and their Adduct with Nitrogen Donar Bases." International Journal of Advance Research, Ideas and Innovations in Technology 2.6 (2016). www.IJARIIT.com.
Abstract
Chloro lanthanu (III) trithiophosphates (RO)(S)(P)(S)2LaCl where R = Me,Et, nPr, iPr, nBu, sBu, iBu , iAm, cyclohexyl, Phenyl,were prepared in the methanolic solution of LaCl3 and dipotassium salt of trithiophosphates.Addition complexes of the type (RO)(S)(P)(S)2LaCl .nL(where n=1,L=(C6H4N)2 1-10-phenanthroline and (C5H4N)2 2,2 -bipyridyl were prepared by reaction of chloro Lanthanum (III) trithiophosphate and nitrogen donar bases in dry methanol . These newly synthesized derivatives have been characterized by elemental analysis, moleculer weight measurement, I R ,13C ,31P spectral studies. Coordination no of three and five are suggested for La (III) in these derivatives. Key Words : La(III) ; 1-10-phenanthroline ; 2,2 -bipyridyl Corrosponding Author;[email protected]